GLIDDEN PAINT -- CAMOUFLAGE EARTH BROWN SPRAY, ZY1901 ======================================================= MSDS Safety Information ======================================================= FSC: 8010 MSDS Date: 03/14/1997 MSDS Num: CGSRX LIIN: 00N084337 Product ID: CAMOUFLAGE EARTH BROWN SPRAY, ZY1901 MFN: 01 Responsible Party Cage: JO648 Name: GLIDDEN PAINT Address: 925 EUCLID AVE City: CLEVELAND OH 44115 Info Phone Number: 800-545-2643 Emergency Phone Number: 800-545-2643 Published: Y ======================================================= Contractor Summary ======================================================= Cage: JO648 Name: GLIDDEN PAINT Address: 925 EUCLID AVE City: CLEVELAND OH 44115 Phone: 800-545-2643 Cage: 01PD6 Name: GLIDDEN PAINT, ICI PAINTS Address: 925 EUCLID AVE City: CLEVELAND OH 44115 Phone: 800-545-2643/216-344-8207 ======================================================= Ingredients ======================================================= Cas: 68476-86-8 RTECS #: 1004627HP Name: HYDROCARBON PROPELLANT (PROPANE/ISOBUTANE); (PETROLEUM GASES, LIQUEFIED, SWEETENED) % Wt: 30-40 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 108-88-3 RTECS #: XS5250000 Name: TOLUENE; (BENZENE, METHYL-) (SARA 313) (CERCLA). LD50:(ORAL,RAT) 5000 MG/KG. % Wt: 10-20 OSHA PEL: 200 PPM ACGIH TLV: 50 PPM, S EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 71-43-2 RTECS #: CY1400000 Name: BENZENE (SARA 313) (CERCLA). %:0.01-0.1. OSHA PEL:1 PPM; 5 PPM STEL (MFR). % Wt: <0.1 OSHA PEL: SEE INGREDIENT ACGIH TLV: 10 PPM EPA Rpt Qty: 10 LBS DOT Rpt Qty: 10 LBS ------------------------------ Cas: 67-64-1 RTECS #: AL3150000 Name: ACETONE (SARA 313) (CERCLA). LD50:(ORAL,RAT) 5800 MG/KG. % Wt: 20-30 OSHA PEL: 1000 PPM ACGIH TLV: 750 PPM;1000 STEL EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 8052-41-3 RTECS #: WJ8925000 Name: STODDARD SOLVENT; (MINERAL SPIRITS). LD50:(ORAL,RAT) 4.7 GM/KG. % Wt: 1-5 OSHA PEL: 500 PPM ACGIH TLV: 100 PPM ------------------------------ Cas: 64742-89-8 RTECS #: 1003161VN Name: VM & P NAPHTHA; (SOLV NAPHTHA (PETRO), LIGHT ALIPHATIC). LD50:(ORAL,RAT) >8 ML/KG. OSHA PEL:300 PPM; 400 PPM STEL (MFR). % Wt: 10-20 OSHA PEL: SEE INGREDIENT ACGIH TLV: 300 PPM (MFR) ------------------------------ Cas: 8052-41-3 RTECS #: WJ8925000 Name: STODDARD SOLVENT; (MINERAL SPIRITS) % Wt: 1-5 OSHA PEL: 500 PPM ACGIH TLV: 100 PPM ------------------------------ Cas: 1333-86-4 RTECS #: FF5800000 Name: CARBON BLACK. LD50:(ORAL,RAT) >10 MG/KG. % Wt: 0.1-1 OSHA PEL: 3.5 MG/M3 ACGIH TLV: 3.5 MG/M3 ------------------------------ Cas: 14464-46-1 RTECS #: VV7325000 Name: SILICA, CRYSTALLINE - CRISTOBALITE; (CRISTOBALITE) % Wt: 0.1-1 OSHA PEL: 0.05 MG/M3 (MFR) ACGIH TLV: 0.05 MG/M3 RDUST ------------------------------ Cas: 14807-96-6 RTECS #: WW2710000 Name: TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC) % Wt: 1-5 OSHA PEL: 20 MPPCF ACGIH TLV: 2 MG/M3 RDUST ------------------------------ Name: SUPDAT:OF MATL INTO LUNG. MOUTH, THROAT & MUC MEMB IRRIT, FATG, DROW, DIZZ &/OR LT HEAD, HDCH, UNCOORD, NAUS, ----------------------------- Name: ING 11:VOMIT, DIARR, GI DISTURBS, CNS DEPRESS, INTOX, CONVLS. CNTNS CHEM THAT IS MOD TOX BY INHAL. OTHER EFTS OF ----------------------------- Name: ING 12:OVEREXP MAY INCL TOX TO LIVER, KIDNEY, LUNGS, CNS, BLOOD, HEART. MAY BE ABSORBED THRU SKIN. BENZENE:IARC ----------------------------- Name: ING 13:HAS DETERM THAT THERE IS SUFFICIENT EVID FOR CARCIN TO HUMANS & EXPTL ANIMALS(GRP 1); NTP HAS DETERM THAT ----------------------------- Name: ING 14:IT IS KNOWN TO BE CARCIN; & OSHA REGULATED AS CARCIN. NOTICE:RPTS HAVE ASSOC RPTD & PRLNG OCCUP OVEREXP ----------------------------- Name: ING 15:TO SOLVS W/PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS MAY BE HARMFUL/ ----------------------------- Name: ING 16:FATAL. CNTNS CRYSTALLINE WHICH IS CONSIDERED HAZ BY INHAL & IS ALSO A KNOWN CAUSE OF SILICOSIS, A ----------------------------- Name: ING 17:NONCANCEROUS LUNG DISEASE. TOLUENE:DELIB INHAL HAS BEEN ASSOC W/NEONATAL EFTS IN HUMANS. DEVEL TOX HAS ----------------------------- Name: ING 18:ALSO BEEN DEMONSTRATED IN LAB ANIMALS BY INHAL. ADDNLY, DELIB INHAL MAY RSLT IN CARD SENSIT WHICH CAN ----------------------------- Name: ING 19:CAUSE IRREG HEART RHYTHM & SUDDEN DEATH. NOTE: TOLUENE APPEARS ON NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK ----------------------------- Name: ING 20:CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HLTH HAZ LIST INFO & SAFE HNDLG & EXPOS INFO(FP N). ----------------------------- Name: SPILL PROC:COMPLETE PPE MUST BE USED DURING CLEANUP. LG SPILLS:SHUT OFF LEAK IF SAFE TO DO SO. DIKE & CONTAIN ----------------------------- Name: ING 22:SPILL. PUMP TO STOR/SALVAGE VESSELS. USE ABSORB TO PICK UP EXCESS RESIDUE. KEEP SALVAGEABLE MATL & RINSE ----------------------------- Name: ING 23:WATER OUT OF SEWERS & WATER COURSES. SM SPILLS:USE ABSORB TO PICK UP RESIDUE & DISPOSE OF PROPERLY. ----------------------------- Name: RESP PROT:IF SUCH CONDITIONS CANNOT BE AVOIDED, USE APPROPRIATE NIOSH APPROVED RESPIRATORY PROTECTION AS DIRECTED. ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: SEE INGREDIENTS. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: YES IARC: YES OSHA: NO Effects of Exposure: INHAL:IRRIT OF RESP TRACT. PRLNG INHAL MAY LEAD TO MUC MEMB IRRIT, FATG, DROW, DIZZ &/OR LT HEAD, HDCH, UNCOORD, NAUS, VOMIT, ABDOM PAIN, COUGH, DFCLTY W/SPEECH, CNS DEPRESS, RESP PROBS, INTOX, CONFUSN, ANESTH EFT/NARCOS, DFCLTY OF BRTHG, B LOOD ABNORMS, LIVER DMG, KIDNEY DMG, LOSS OF CONSCIOUSNESS, (EFTS OF OVEREXP) Explanation Of Carcinogenicity: CARBON BLACK:IARC MONOGRAPHS, VOL 65, PG 24-27, 1995:GRP 2B. SILICA, CRYSTALLINE-CRISTOBALITE:IARC MONOGRAPHS, (SUPDAT) Signs And Symptions Of Overexposure: HLTH HAZ:RESP FAILURE, ASPHY, DEATH. SKIN CONT:IRRIT. PRLNG/RPTD CONT CAN CAUSE DERM, DEFAT. CONT MAY RSLT IN DERMAL ABSORPTION OF INGS WHICH MAY CAUSE CNS DEPRESS. EYE CONT:IRRIT. PRLNG/RPTD CONT CAN CAUSE CONJ, BLURRED VISION, TEARING, RE DNESS, SEV IRRIT, CORNEAL INJURY. INGEST:MAY CAUSE LUNG INFLAMM & DMG (SUPDAT) Medical Cond Aggravated By Exposure: EYE, SKIN, RESPIRATORY DISORDERS, LUNG DISORDERS, ASTHMA-LIKE CONDITIONS, CARDIAC ABNORMALITIES, KIDNEY DISORDERS, LIVER DISORDERS. First Aid: INHAL:REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG. GET EMER MED ATTN. HAVE TRAINED PERS GIVE OXYG IF NEC. GET MED HELP FOR ANY BRTHG DFCLTY. REMOVE TO FRESH AIR IF INHAL CAUSES EYE WATERING, HDCHS, DIZZ/OTHER DISCOMFORT. SKIN:FLU SH W/WATER. THEN WASH THORO W/SOAP & WATER. REMOVE & WASH CONTAM CLTHG BEFORE RE-USE. EYES:FLUSH IMMED W/LG AMTS OF WATER, ESP UNDER LIDS FOR AT LST 15 (SUPDAT) ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: COMPLY W/ALL APPLIC HLTH & ENVIRON REGS. ELIM ALL SOURCES OF IGNIT. VENT AREA. VENT AREA W/EXPLO-PROOF EQUIP. SPILLS MAY BE COLLECTED W/ABSORB MATLS. USE NON-SPARKING TOOLS. EVACUATE ALL UNNEC PERS. PLACE COLLECTED MATL IN PROPER CNTNR. (IN G 22) Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS (FP N). DISPOSE I/A/W ALL APPLICABLE REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS. Handling And Storage Precautions: STORE <80F. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. USE ONLY W/ADEQ VENT. DO NOT TAKE INTERNALLY. AVOID CONTACT W/SKIN & EYES & BREATHING OF VAPORS. Other Precautions: KEEP OUT OF REACH OF CHILDREN. KEEP CONTAINERS TIGHTLYCLOSED & UPRIGHT WHEN NOT IN USE. EMPTY CONTAINERS MAY CONTAIN HAZRESIDUES. GROUND EQUIPMENT WHEN TRANSFERRING TO PREVENT ACCUMULATION OFSTATIC CHARGE. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: SCC Flash Point Text: 20.0F,-6.7C Lower Limits: 2.5% Upper Limits: 13.3% Extinguishing Media: DRY CHEMICAL OR FOAM, WATER FOG, CARBON DIOXIDE. Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). WATER MAY BE USED TO COOL & PROTECT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard: CLSD CNTNRS MAY EXPLODE/BURST WHEN EXPOS TO EXTREME HEAT/FIRE. VAPS MAY IGNITE EXPLO AT AMBIENT TEMPS & ARE HVR/AIR & MAY TRAVEL LONG DISTS TO SOURCE OF(SUPDAT) ======================================================= Control Measures ======================================================= Respiratory Protection: CONTROL ENVIRON CONCS BELOW APPLIC STDS. WHERE RESP PROT IS REQD, USE ONLY NIOSH APPRVD RESPS I/A/W OSHA STD 29 CFR 1910.134. AVOID CNDTNS WHICH RSLT IN FORM OF INHALABLE PARTICLES SUCH AS SPRAYING/ABRADING (SANDING) PAINTED SURFS. Ventilation: PROVIDE DILUTION VENT/LOCAL EXHAUST TO PREVENT BUILD-UP OF VAPORS. USE EXPLO-PROOF EQUIPMENT. USE NON-SPARKING EQUIP. Protective Gloves: IMPERVIOUS GLOVES. Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS (FP N). Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA (FP N). IMPERVIOUS CLOTHING, APRON, BOOTS. Work Hygienic Practices: WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE EATING OR SMOKING. Supplemental Safety and Health: EXPLO HAZ:IGNIT & FLASH BACK. MAY DECOMP UNDER FIRE CNDTNS EMITTING IRRIT &/OR TOX GASES. EXPLAN OF CARCIN:VOL 68, 1997:GRP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO BE CARCIN. FIRST AID PROC:MINS. IF IRRIT/OTHER EFTS PERSIST, GET MED TREATMENT. INGEST:GET MED TREATMENT IMMED. EFTS OF OVEREXP:DUE TO ASPIR ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >133F,>56C Spec Gravity: 0.714 Appearance and Odor: LIQUID. Percent Volatiles by Volume: 95.06 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: ELEVATED TEMPERATURES, CONTACT W/OXIDIZING AGENT, SPARKS, OPEN FLAME. IGNITION SOURCES. Materials To Avoid: OXIDIZERS, ACIDS, BASES, AMINES, NITRIC ACID, VINYL POLYMERS. NITRATES. Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, ACRID FUMES, ALDEHYDES, TOXIC GASES. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: CAMOUFLAGE EARTH BROWN SPRAY, ZY1901 Cage: JO648 Assigned IND: Y Company Name: GLIDDEN PAINT Street: 925 EUCLID AVE City: CLEVELAND OH Zipcode: 44115 Health Emergency Phone: 800-545-2643 Label Required IND: Y Date Of Label Review: 03/25/1998 Status Code: C Label Date: 03/25/1998 Origination Code: G Chronic Hazard IND: Y Eye Protection IND: YES Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Severe Contact Hazard: Severe Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: ACUTE:INHAL:IRRIT; FATG, DROW, DIZZ &/OR LT HEAD, HDCH, UNCOORD, NAUS, VOMIT, ABDOM PAIN, COUGH, DFCLTY W/SPEECH, CNS DEPRESS, RESP PROBS, INTOX, CONFUSN, ANESTH EFT/NARCOS, DFCLTY OF BRTHG, BLOOD ABNORMS, LIVER DMG, KIDNEY DMG, LOSS OF CON SCIOUSNESS, RESP FAILURE, ASPHY, DEATH. SKIN:IRRIT; DERM, DEFAT. ABSORPTION-CNS DEPRESS. EYE:IRRIT; CONJ, BLURRED VISION, TEARING, REDNESS, SEV IRRIT, CORNEAL INJURY. INGEST:LUNG INFLAMM & ASPIR DMG. IRRIT, FATG, CNS EFTS, GI DISTURBS. CHRO NIC:CANCER HAZ. CARBON BLACK & SILICA, CRYSTALLINE-CRISTOBALITE ARE LISTED AS ANIMAL & HUMAN LUNG CARCINS(FP N). TOLUENE APPEARS ON NAVY OCCUP CHEM REPRO HAZS LIST(FP N). ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.