SHERWIN-WILLIAMS CO -- FLUORESCENT SPRAY PAINT, 3106 GREEN ======================================================= MSDS Safety Information ======================================================= FSC: 8010 NIIN: 00-132-2861 MSDS Date: 09/01/1996 MSDS Num: CHXPW Product ID: FLUORESCENT SPRAY PAINT, 3106 GREEN MFN: 02 Responsible Party Cage: 54636 Name: SHERWIN-WILLIAMS CO Address: 31500 SOLON RD City: SOLON OH 44139 Info Phone Number: 800-777-2966 Emergency Phone Number: 215-566-2917 Review Ind: Y Published: Y ======================================================= Contractor Summary ======================================================= Cage: 54636 Name: SHERWIN-WILLIAMS CO THE Address: 101 PROSPECT AVE NW City: CLEVELAND OH 44115-1042 Phone: 216-566-2242 ======================================================= Item Description Information ======================================================= Item Name: LACQUER,FLOURESCEN ======================================================= Ingredients ======================================================= Cas: 74-98-6 RTECS #: TX2275000 Name: PROPANE. VP: 760 % Wt: 14 OSHA PEL: 1000 PPM ACGIH TLV: ASPHYXIANT ------------------------------ Cas: 106-97-8 RTECS #: EJ4200000 Name: BUTANE. VP: 760 % Wt: 8 OSHA PEL: 800 PPM ACGIH TLV: 800 PPM ------------------------------ Cas: 110-54-3 RTECS #: MN9275000 Name: HEXANE (CERCLA). VP: 127 % Wt: 11 OSHA PEL: 500 PPM ACGIH TLV: 50 PPM EPA Rpt Qty: 1 LB DOT Rpt Qty: 1 LB ------------------------------ Cas: 107-83-5 RTECS #: SA2995000 Name: PENTANE, 2-METHYL-; (ISOHEXANE ISOMERS). VP: 250 % Wt: 4 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 64742-89-8 RTECS #: 1003161VN Name: VM & P NAPHTHA. VP: 12 % Wt: 16 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 1330-20-7 RTECS #: ZE2100000 Name: XYLENE (SARA 313) (CERCLA). VP: 5.9 % Wt: 1 OSHA PEL: 100 PPM ACGIH TLV: 100 PPM; 150 STEL EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 67-64-1 RTECS #: AL3150000 Name: ACETONE (SARA 313) (CERCLA). VP: 180 % Wt: 12 OSHA PEL: 1000 PPM ACGIH TLV: 750 PPM; 1000 STEL EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 471-34-1 RTECS #: FF9335000 Name: CALCIUM CARBONATE % Wt: 3.3 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 7727-43-7 RTECS #: CR0600000 Name: BARIUM SULFATE (CONTAINING INGREDIENT 10) % Wt: 18.3 OSHA PEL: 15 MG/M3 TDUST ACGIH TLV: 10 MG/M3 TDUST ------------------------------ Cas: 7440-39-3 RTECS #: CQ8370000 Name: BARIUM (SARA 313) % Wt: 10.8 OSHA PEL: 0.5 MG/M3 ACGIH TLV: N/K (FP N) ------------------------------ RTECS #: 9999999VO Name: VOLATILE ORGANIC COMPOUND AS PERCENT BY WEIGHT PER BAAQMD RULE 49: 52.9; VOC TOTAL: 3.77 LBS/GAL OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- Name: SUPDAT: OVEREXP TO SOLVENTS W/PERMANENT BRAIN & NERVOUS SYSTEM DMG. WARNING:THESE PRODS CONTAIN CHEM/S KNOWN TO ----------------------------- Name: ING 12: STATE OF CALIFORNIA TO CAUSE CANCER & BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. ----------------------------- Name: HNDLG/STOR PRECS: UNTIL ALL VAPS ARE GONE: KEEP AREA VENTD - DO NOT SMOKE - EXTING ALL FLAMES, PILOT LIGHTS & ----------------------------- Name: ING 14: HEATERS - TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF IGNIT. CONSULT NFPA CODE. USE ----------------------------- Name: ING 15: APPRVD BONDING & GROUNDING PROCS. CONTENTS UNDER PRESS. DO NOT PUNCTURE, INCIN OR EXPOSE TO TEMPS >330F. ----------------------------- Name: ING 16: HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT WATER & OTHER HEAT SOURCES COULD CAUSE CNTNR TO BURST. DO ----------------------------- Name: ING 17: NOT TAKE INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN. ----------------------------- Name: OTHER PRECS: AS NUISANCE PARTICULATES (LISTED "AS DUST" IN INGRED SECTION) WHICH MAY BE PRESENT AT HAZ LEVELS ----------------------------- Name: ING 19: ONLY DURING SANDING OR ABRADING OF DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED, THE APPLIC LIMITS FOR ----------------------------- Name: ING 20: NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (TDUST), OSHA PEL 15 MG/M3 (TDUST), 5 MG/M3 (RESPIRABLE FRACTION). ----------------------------- Name: RESP PROT: NON-VOLATILE MATERIALS IN INGREDIENT SECTION. ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF EXCESSIVE EXPOS TO VAPORS OR SPRAY MISTS. REDNESS & ITCHING OR BURNING SENSAT ION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOSURE. PRLNGD (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: HLTH HAZ: OVEREXP TO HEXANE MAY CAUSE DMG TO NERVE TISSUES OF ARMS & LEGS (PERIPHEREAL NEUROPATHY), RESULTING IN MUSCULAR WEAK & LOSS OF COORDINATION. THIS EFT MAY BE INCREASED BY PRESENCE OF METHYL ETHYL KETONE. PRLNGD OVEREXP TO SOLV INGR EDS LISTED MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, BLOOD-FORMING, (SUPDAT) Medical Cond Aggravated By Exposure: NONE GENERALLY RECOGNIZED. First Aid: INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BRTHG. KEEP WARM & QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. EYES: FLUSH EYES W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 M INUTES. GET MED ATTN. INGEST: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. SEEK MED ATTN. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE APPLIC EPA HAZ WASTE NUMBERS. DO NOT INCINERATE. DEPRESSURIZE CNTNR. DISPOSE OF I/A/W FED, STATE & LOCAL REGS REGARDING POL LUTION. Handling And Storage Precautions: CONTENTS ARE EXTREMELY FLAM. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. VAPS WILL ACCUMULATE READILY & MAY IGNITE EXPLOSIVELY. DURING USE & Other Precautions: INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS CANBE HARMFUL/FATAL. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOIDCONTACT W/SKIN & EYES. WASH HANDS AFTER USING. THESE COATINGS MAY CONTAINMATLS CLASSIFIED ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: PMCC Flash Point Text: <0F,<-18C Lower Limits: 0.9% Upper Limits: 13.1% Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N). WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREF. WATER MAY BE USED TO COOL CLSD CNTNRS(SUPDAT) Unusual Fire/Explosion Hazard: ISOLATE FROM HEAT, ELEC EQUIP, SPARKS & OPEN FLAME. CLOSED CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO HOT SURFS REQS SPECIAL (SUPDAT) ======================================================= Control Measures ======================================================= Respiratory Protection: IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMITS VY BENT, WEAR NIOSH APPRVD, PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESP. WHEN SANDING OR ABRADING DRIED FILM, WEAR DUST/MIST RESP APPRVD BY NIOSH FOR PROT AGAINST Ventilation: LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS MAINTAINED BELOW APPLIC LIMS. REFER TO OSHA STDS 1910.98, 107, 108. Protective Gloves: CHEMICAL RESISTANT GLOVES. Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N). Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: FIRE FIGHT PROC: TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT OR EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZS: PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE A HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. EFTS OF OV EREXP: CARDIOVASCULAR & REPRO SYS. REPORTS HAVE ASSOC RPTD & PRLNGD ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: <0F,<-18C Vapor Pres: SEE INGS Vapor Density: HVR/AIR Spec Gravity: 0.857 (FP N) Evaporation Rate & Reference: FASTER THAN ETHER Appearance and Odor: NONE SPECIFIED BY MANUFACTURER. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: NONE KNOWN. Hazardous Decomposition Products: BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Responsible Party Cage: 54636 Trans ID NO: 137554 Product ID: FLUORESCENT SPRAY PAINT, 3106 GREEN MSDS Prepared Date: 09/01/1996 Review Date: 01/14/1999 MFN: 2 Multiple KIT Number: 0 ======================================================= Detail DOT Information ======================================================= DOT PSN Code: LFD DOT Proper Shipping Name: PAINT DOT PSN Modifier: INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS, VARNISH, POLISH, LIQUID FILLER, AND LIQUID LACQUER BASE Hazard Class: 3 UN ID Num: UN1263 DOT Packaging Group: II Label: FLAMMABLE LIQUID Special Provision: B52,T7,T30 Packaging Exception: 150 Non Bulk Pack: 173 Bulk Pack: 242 Max Qty Pass: 5 L Max Qty Cargo: 60 L Vessel Stow Req: B ======================================================= Detail IMO Information ======================================================= IMO PSN Code: LCP IMO Proper Shipping Name: PAINT OR PAINT RELATED MATERIAL IMO PSN Modifier: (INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS, VARNISH, POLISH, LIQUID FILLER AND LIQUID LACQUER BASE) OR (INCLUDING PAINT THINNING OR REDUCING COMPOUND) o IMDG Page Number: 3268 UN Number: 1263 UN Hazard Class: 3.2 IMO Packaging Group: I/II * Subsidiary Risk Label: - EMS Number: 3-05 MED First Aid Guide NUM: 310 ======================================================= Detail IATA Information ======================================================= IATA PSN Code: SXI IATA UN ID Num: 1263 IATA Proper Shipping Name: PAINT IATA PSN Modifier: (INCLUDING PAINT,LACQUER,ENAMEL,STAIN,SHELLAC,VARNISH,POLISH,LIQUID FILLER AND LIQUID LACQUER BASE) IATA UN Class: 3 IATA Label: FLAMMABLE LIQUID UN Packing Group: II Packing Note Passenger: 305 Max Quant Pass: 5L Max Quant Cargo: 60L Packaging Note Cargo: 307 Exceptions: A7,A72 ======================================================= Detail AFI Information ======================================================= AFI PSN Code: SXI AFI Proper Shipping Name: PAINT OR PAINT RELATED MATERIAL AFI PSN Modifier: (INCLUDING PAINT,LACQUER,ENAMEL,STAIN,SHELLAC SOLUTIONS,VARNISH,POLISH,LIQUID FILLER AND LIQUID LACQUER BASE) OR (INCLUDING PAINT THINNING OR REDUCING COMPOUNDS) AFI Hazard Class: 3 AFI UN ID NUM: UN1263 AFI Packing Group: II Special Provisions: P5 Back Pack Reference: A7.3 ======================================================= HAZCOM Label ======================================================= Product ID: FLUORESCENT SPRAY PAINT, 3106 GREEN Cage: 54636 Company Name: SHERWIN-WILLIAMS CO THE Street: 101 PROSPECT AVE NW City: CLEVELAND OH Zipcode: 44115-1042 Health Emergency Phone: 215-566-2917 Label Required IND: Y Date Of Label Review: 10/07/1998 Status Code: C Label Date: 10/07/1998 Origination Chronic Hazard IND: Y Eye Protection IND: YES Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: FLAMMABLE. ACUTE: EYES/SKIN: IRRITATION, REDNESS AND ITCHING OR BURNING SENSATION. INHALATION: RESPIRATORY SYSTEM IRRITATION. MAY CAUSE NERVOUS SYSTEM DEPRESSION, HEADACHE, DIZZINESS, NAUSEA, LOSS OF COORDINATION, UNCONSCIOUSNESS AND POSSIB LY DEATH. CHRONIC: HEXANE MAY CAUSE DAMAGE TO NERVE TISSUE OF ARMS AND LEGS RESULTING IN MUSCULAR WEAKNESS AND LOSS OF COORDINATION. OVEREXPOSURE TO SOLVENTS MAY CAUSE ADVERSE EFFECTS TO THE LIVER, URINARY, BLOOD-FORMING, CARDIOVASCULAR AND REPRODUCTIVE SYSTEMS AND HAS BEEN ASSOCIATED WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.