3M GENERAL OFFICES 3M CENTER -- SCOTCHGARD(TM) BRAND PROTECTOR FOR FABRICS - AEROSOL STAIN & WATER REPELLENT MATERIAL SAFETY DATA SHEET NSN: 8030001169255 Manufacturer's CAGE: 04963 Part No. Indicator: B Part Number/Trade Name: SCOTCHGARD(TM) BRAND PROTECTOR FOR FABRICS =========================================================================== General Information =========================================================================== Item Name: AEROSOL STAIN & WATER REPELLENT Company's Name: 3M GENERAL OFFICES, 3M CENTER Company's City: ST PAUL Company's State: MN Company's Country: US Company's Zip Code: 55144-1000 Company's Emerg Ph #: 612-733-1110 Company's Info Ph #: 612-733-1110 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 003 Status: FE Date MSDS Prepared: 19FEB90 Safety Data Review Date: 07MAR91 Supply Item Manager: GSA Preparer's State: NK MSDS Serial Number: BJXFS Unit Of Issue: CN Unit Of Issue Container Qty: 16 OZ CAN Type Of Container: METAL =========================================================================== Ingredients/Identity Information =========================================================================== Proprietary: NO Ingredient: METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III) Ingredient Sequence Number: 01 Percent: 92.-94. NIOSH (RTECS) Number: KJ2975000 CAS Number: 71-55-6 OSHA PEL: 350 PPM/450 STEL ACGIH TLV: 350 PPM/450STEL;9192 Other Recommended Limit: NONE SPECIFIED ------------------------------------- Proprietary: NO Ingredient: CARBON DIOXIDE Ingredient Sequence Number: 02 Percent: 3.-4. NIOSH (RTECS) Number: FF6400000 CAS Number: 124-38-9 OSHA PEL: 5000 PPM ACGIH TLV: 5000PPM/30000STEL;93 Other Recommended Limit: NONE SPECIFIED ------------------------------------- Proprietary: NO Ingredient: FLUOROCHEMICAL POLYMER Ingredient Sequence Number: 03 Percent: .5-1.5 NIOSH (RTECS) Number: 1005443FP OSHA PEL: NONE ACGIH TLV: NONE Other Recommended Limit: NONE SPECIFIED ------------------------------------- Proprietary: NO Ingredient: METHYLAL (DIMETHOXYMETHANE) Ingredient Sequence Number: 04 Percent: 1.-3. NIOSH (RTECS) Number: PA8750000 CAS Number: 109-87-5 OSHA PEL: 1000 PPM ACGIH TLV: 1000 PPM; 9192 Other Recommended Limit: NONE SPECIFIED ------------------------------------- Proprietary: NO Ingredient: TERT-BUTYL ALCOHOL (SARA III) Ingredient Sequence Number: 05 Percent: <2.0 NIOSH (RTECS) Number: EO1925000 CAS Number: 75-65-0 OSHA PEL: 100 PPM ACGIH TLV: 100PPM 9394 Other Recommended Limit: NONE SPECIFIED ------------------------------------- Proprietary: NO Ingredient: SEC-BUTYL ALCOHOL (SARA III) Ingredient Sequence Number: 06 Percent: <2.0 NIOSH (RTECS) Number: EO1750000 CAS Number: 78-92-2 OSHA PEL: 150 PPM ACGIH TLV: 100 PPM; 9293 Other Recommended Limit: NONE SPECIFIED =========================================================================== Physical/Chemical Characteristics =========================================================================== Appearance And Odor: COLORLESS, LIQUID IN AEROSOL CAN, CHLORINATED SOLVENT ODOR Boiling Point: 175F,79C Vapor Pressure (MM Hg/70 F): 100. @ 20C Vapor Density (Air=1): 4.55/AIR=1 Specific Gravity: 1.300(WATER=1) Evaporation Rate And Ref: .40 (ETHER=1) Solubility In Water: <0.1% NEGLIGIBLE Percent Volatiles By Volume: 99.50 =========================================================================== Fire and Explosion Hazard Data =========================================================================== Flash Point: NONE Lower Explosive Limit: 6.30 Upper Explosive Limit: 15.50 Extinguishing Media: WATER, CO2, FOAM, DRY CHEMICAL Special Fire Fighting Proc: TREAT AS A PRESSURIZED CONTAINER Unusual Fire And Expl Hazrds: EXCESSIVE HEAT WILL CAUSE THE AEROSOL CANS TO EXPLODE. =========================================================================== Reactivity Data =========================================================================== Stability: YES Hazardous Decomp Products: EXPOSURE TO TEMPERATURES IN EXCESS OF 600F MAY PRODUCE TOXIC CHLORINATED BY-PRODUCTS. Hazardous Poly Occur: NO =========================================================================== Health Hazard Data =========================================================================== Health Haz Acute And Chronic: INHALATION:OVEREXPOSURE MAY BE HARMFUL. SYMPTOMS OF OVEREXPOSURE MAY INCLUDE RESPIRATORY SYSTEM IRRITATION & TEMPORARY NERVOUS SYSTEM IMPAIRMENT. MAY CAUSE MILD LIVER & KIDNEY INJURY & HEART RHYTHM DISTURBANCES. DELIBERATE MISUSE BY CONCENTRATION & INHALATION OF VAPORS MAY BE FATAL/MAY CAUSE DEATH. Signs/Symptoms Of Overexp: INHALE:RESPIRATORY SYSTEM IRRITATION, TEMPORARY NERVOUS SYSTEM IMPAIRMENT:DIZZI, NAUSEA, HEADACHE, GIDDINESS & LOSS OF CONSCIOUSNESS. EYES:STUDIES INDICATE PRODUCT IS PRACTICALLY NON- IRRITATING TO EYES OF LAB TEST ANIMALS. SKIN:NEITHER IRRITATING NOR SENSITIZING TO SKIN OF LAB TEST ANIMALS. INGESTION:NON-TOXIC ORALLY. Emergency/First Aid Proc: EYE:IMMED FLUSH W/PLENTY OF WATER FOR 10 MINS HOLDING LIDS OPEN. CALL PHYSICIAN. SKIN:WASH AFFECTED AREA W/SOAP & WATER. INHALE:IF SYMPTOMS OCCUR, REMOVE PERSON TO FRESH AIR. IF SYMPTOMS CONTINUE, CALL PHYSICIAN. NOTE TO PHYSICIAN:1,1,1-TRICHLOROETHANE MAY INCREASE MYOCARDIAL IRRIT. DO NOT ADMIN SYMPATHOMIMETIC DRUGS(I.E. ADRENALINE)UNLESS ABSOLUTELY NECESSARY.TREATMENT BASE ON JUDGEMENT OF DOCTOR =========================================================================== Precautions for Safe Handling and Use =========================================================================== Steps If Matl Released/Spill: COLLECT SPILL, OBSERVING ALL PRECAUTIONS. VENTILATE AREA. CLEAN UP RESIDUE. PLACE IN AN APPROVED METAL CONTAINER & SEAL. Waste Disposal Method: DO NOT PUNCTURE CANS/BURN IN HOUSEHOLD INCINERATOR.BURN IN HEAVY-DUTY INCINERATOR DESIGNED FOR AEROSOL CANS. SINGLE CAN:BLEED CAN OF PROPELLANT IN WELL VENTED AREA.EMPTY CAN MAY BE BURIED IN SANITARY LANDFILL.CONSULT APPLICABLE REGS BEFORE DISPOSAL Precautions-Handling/Storing: DO NOT STORE ABOVE 120F. USE ONLY AS DIRECTED. IF APPLICATION REQUIRES MORE THAN 1 CAN, WAIT 60 MINS BETWEEN SPRAYING EACH CAN. KEEP FROM HEAT SOURCES Other Precautions: KEEP SMALL CHILDREN & PETS OUT OF AREA UNTIL TREATMENT HAS THOROUGHLY DRIED. KEEP OUT OF REACH OF CHILDREN. NOTE:ONCE THE PRODUCT HAS DRIED, THESE WARNINGS DO NOT APPLY. KEEP FROM HEAT SOURCES & OPEN FLAMES, OVENS, STOVES, DRYERS, ETC... =========================================================================== Control Measures =========================================================================== Respiratory Protection: MAINTAIN CROSS VENTILATION THROUGH USE OF FANS & OPENING ALL DOORS & WINDOWS UNTIL THE ARTICLE IS DRY. DO NOT USE IN SMALL ROOMS, BATHROOMS OR CLOSETS. USE OUTDOORS WHERE POSSIBLE. Ventilation: USE ONLY IN AREAS ADEQUATELY VENTILATED TO REMOVE VAPORS & PREVENT VAPOR BUILDUP. USE WITHOUT VENT MAY BE HARMFUL/FATAL Suppl. Safety & Health Data: SEE FILE FOR ANY ADDITIONAL INFORMATION =========================================================================== Transportation Data =========================================================================== Trans Data Review Date: 91066 DOT PSN Code: DTJ DOT Symbol: D DOT Proper Shipping Name: CONSUMER COMMODITY DOT Class: ORM-D DOT Label: NONE IMO PSN Code: AKH IMO Proper Shipping Name: AEROSOLS/AEROSOL PRODUCT IMO Regulations Page Number: SEE 9022 IMO UN Number: 1950 IMO UN Class: 9 IMO Subsidiary Risk Label: - IATA PSN Code: ALS IATA UN ID Number: 1950 IATA Proper Shipping Name: AEROSOLS, 30, * IATA UN Class: 2.1 IATA Label: FLAMMABLE GAS AFI PSN Code: ALS AFI Prop. Shipping Name: AEROSOLS, NONFLAMMABLE, N.O.S. AFI Class: FORB AFI Basic Pac Ref: FORBIDDEN MMAC Code: NK N.O.S. Shipping Name: CONSUMER COMMODITY ORM-D. =========================================================================== Disposal Data =========================================================================== =========================================================================== Label Data =========================================================================== Label Required: YES Label Status: G Common Name: SCOTCHGARD(TM) BRAND PROTECTOR FOR FABRICS Special Hazard Precautions: INHALATION:OVEREXPOSURE MAY BE HARMFUL. SYMPTOMS OF OVEREXPOSURE MAY INCLUDE RESPIRATORY SYSTEM IRRITATION & TEMPORARY NERVOUS SYSTEM IMPAIRMENT. MAY CAUSE MILD LIVER & KIDNEY INJURY & HEART RHYTHM DISTURBANCES. DELIBERATE MISUSE BY CONCENTRATION & INHALATION OF VAPORS MAY BE FATAL/MAY CAUSE DEATH. INHALE: RESPIRATORY SYSTEM IRRITATION, TEMPORARY NERVOUS SYSTEM IMPAIRMENT:DIZZI, NAUSEA, HEADACHE, GIDDINESS & LOSS OF CONSCIOUSNESS. EYES:STUDIES INDICATE PRODUCT IS PRACTICALLY NON-IRRITATING TO EYES OF LAB TEST ANIMALS. SKIN: NEITHER NON-TOXIC ORALLY. Label Name: 3M GENERAL OFFICES, 3M CENTER Label City: ST PAUL Label State: MN Label Zip Code: 55144-1000 Label Country: US Label Emergency Number: 612-733-1110