AMERICAN INTERNATIONAL INDUSTR -- EUROPEAN SECRETS NAIL LACQUER ======================================================= MSDS Safety Information ======================================================= FSC: 8530 MSDS Date: 09/01/1993 MSDS Num: CFTDF LIIN: 00D007077 Product ID: EUROPEAN SECRETS NAIL LACQUER MFN: 01 Responsible Party Cage: 6N767 Name: AMERICAN INTERNATIONAL INDUSTRIES Address: 2220 GASPAR AVE. City: LOS ANGELES CA 90040 Info Phone Number: 213-728-2999/FAX-1829 Emergency Phone Number: 213-728-2999 800-424-9300(CHEMTREC) Preparer's Name: UNKNOWN Review Ind: Y Published: Y ======================================================= Contractor Summary ======================================================= Cage: 6N767 Name: AMERICAN INTERNATIONAL CHEMICAL INC Address: 17 STRATHMORE RD City: NATICK MA 01760 Phone: 800-238-0001 ======================================================= Ingredients ======================================================= Cas: 141-78-6 RTECS #: AH5425000 Name: ETHYL ACETATE (CERCLA) % Wt: 20-35 Other REC Limits: NONE RECOMMENDED OSHA PEL: 400 PPM ACGIH TLV: 400 PPM; 9596 EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 123-86-4 RTECS #: AF7350000 Name: N-BUTYL ACETATE (CERCLA) % Wt: 20-35 Other REC Limits: NONE RECOMMENDED OSHA PEL: 150 PPM ACGIH TLV: 150 PPM/200STEL;9596 EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 67-63-0 RTECS #: NT8050000 Name: ISOPROPANOL (SARA 313) % Wt: 5-10 Other REC Limits: NONE RECOMMENDED OSHA PEL: 400 PPM ACGIH TLV: 400 PPM/500STEL;9596 ------------------------------ Cas: 84-74-2 RTECS #: TI0875000 Name: DIBUTYL PHTHALATE (SARA 313) (CERCLA) % Wt: 5-10 Other REC Limits: NONE RECOMMENDED OSHA PEL: 5 MG/M3 ACGIH TLV: 5 MG/M3; 9596 EPA Rpt Qty: 10 LBS DOT Rpt Qty: 10 LBS ------------------------------ Cas: 76-22-2 RTECS #: EX1225000 Name: CAMPHOR, SYNTHETIC % Wt: 0.2-2 Other REC Limits: NONE RECOMMENDED OSHA PEL: 2 MG/M3 ACGIH TLV: 2 PPM/3 STEL; 9596 ------------------------------ Cas: 9004-70-0 RTECS #: QW0970000 Name: COLLODION (WET NITROCELLULOSE) % Wt: 7-15 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: LD50 ORAL RAT HAS NOT BEEN ESTABLISHED Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYES:MAY CAUSE IRRITATION.SKIN:MAY CAUSE IRRITATION.INHAL:MAY CAUSE RESPIRATORY IRRITATION AND CNS DEPRESSION.INGEST:MAY CAUSE GASTROINTESTINAL IRRITATION.CHRONIC:LONG TERM EXPOSURE TO THE SOLVENTS IN THIS PRODUCT HAVE BEEN ASSOCIATED WITH PERMANENT BRAIN AND NERVIOUS SYSTEM DAMAGE. Explanation Of Carcinogenicity: THIS ITEM DOES NOT CONTAIN ANY INGREDIENT AT 0.1% OR GREATER WHICH IS A CARCINOGEN. Signs And Symptions Of Overexposure: EYES:BURNING,TEARING,REDNESS,SWELLING.SKIN:REDNESS,BURNING,DERMATITIS. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MFR. First Aid: EYES:FLUSH WITH WATER UNTIL ALL TRACES OF THIS MATERIAL ARE GONE.SKIN:REMOVE CONTAMINATED CLOTHING.WASH WITH WATER.INHAL:REMOVE FROM EXPOSURE.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NESCESSARY.INGEST:DO NOT INDUCE VOMITING.GET PROMPT QUALI FIED MEDICAL ATTENTION. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: ELIMINATE SOURCES OF IGNITION.USE PROPER RESPIRATORY AND PROTECTIVE EQUIPMENT.VENTILATE AREA.SOAK UP WITH AN INERT,NON-COMBUSTIBLE ABSORBANT.WASH SPILL AREA.FOR LARGE SPILLS,NOTIFY THE NATIONAL RESPONSE CENTER AT 800-424-8802. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS. Handling And Storage Precautions: STORE IN A COOL,DRY,WELL-VENTILATED PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE.AVOID HEAT,SPARKS AND FLAMES. Other Precautions: NONE ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point Text: 55.0F,12.8C Lower Limits: 1.45 Upper Limits: 8.2 Extinguishing Media: WATER IS THE MOST EFFECT AGENT IN FIGHTING A NITROCELLULOSE FIRE.FOR A SMALLER FIRE USE DRY CHEMICAL,CARBON DIOXIDE,FOAM Fire Fighting Procedures: USE A SELF-CONTAINED BREATHING APPARATUS AND FULL FIRE PROTECTIVE EQUIPMENT.COOL FIRE EXPOSED CONTAINERS WITH WATER FOG. Unusual Fire/Explosion Hazard: SOLVENT MAY EVAPORATE FIRST,CREATING AN EXPLOSION AND FLASHBACK HAZARD.THIS MATERIAL FLOATS ON WATER;AVOID SPREADING BURNING LIQUID. ======================================================= Control Measures ======================================================= Respiratory Protection: USE A NIOSH-MSHA APPROVED RESPIRATOR FOR ORGANIC VAPOR. Ventilation: USE LOCAL EXHAUST AT THE WORKSITE;GENERAL EXHAUST TO MAINTAIN TLV/PEL.USE NON-SPARKING EQUIPMENT. Protective Gloves: IMPERMEABLE. Eye Protection: CHEMICAL SPLASH GOGGLES. Other Protective Equipment: PROVIDE LOCAL EYE WASH STATION. Work Hygienic Practices: USE REASONABLE CARE WITH THIS ITEM.WASH HANDS BEFORE EATING. Supplemental Safety and Health: NONE ======================================================= Physical/Chemical Properties ======================================================= HCC: F3 B.P. Text: 171F-228F Decomp Text: UNKNOWN Vapor Pres: 35-42 Vapor Density: 3.2-3.6 Spec Gravity: 0.948-0.984 Evaporation Rate & Reference: 2-3.3(N-BUTYL ACETATE=1) Solubility in Water: 8-15%;MOD-APPRECIABL Appearance and Odor: COLORED VISCOUS SOLUTION WITH THE ODOR OF ESTERS. Percent Volatiles by Volume: 78-85 Corrosion Rate: UNKNOWN ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HIGH HEAT,SOURCES OF IGNITION. Materials To Avoid: STRONG ACIDS,BASES OR OXIDIZERS. Hazardous Decomposition Products: CARBON DIOXIDE,CARBON MONOXIDE,OXIDES OF NITROGEN.UNDER CERTAIN CIRCUMSTANCES,METHANE,ALDEHYDES,CARBOXYLIC ACIDS,HCN. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Responsible Party Cage: 6N767 Trans ID NO: 6875 Product ID: EUROPEAN SECRETS NAIL LACQUER MSDS Prepared Date: 09/01/1993 Review Date: 12/05/1997 MFN: 1 Net Unit Weight: UNKNOWN AF MMAC Code: NR Multiple KIT Number: 0 Review IND: Y Additional Data: NONE ======================================================= Detail DOT Information ======================================================= DOT PSN Code: LFD DOT Proper Shipping Name: PAINT DOT PSN Modifier: INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS, VARNISH, POLISH, LIQUID FILLER, AND LIQUID LACQUER BASE Hazard Class: 3 UN ID Num: UN1263 DOT Packaging Group: II Label: FLAMMABLE LIQUID Special Provision: B52,T7,T30 Packaging Exception: 150 Non Bulk Pack: 173 Bulk Pack: 242 Max Qty Pass: 5 L Max Qty Cargo: 60 L Vessel Stow Req: B ======================================================= Detail IMO Information ======================================================= IMO PSN Code: LCP IMO Proper Shipping Name: PAINT OR PAINT RELATED MATERIAL IMO PSN Modifier: (INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS, VARNISH, POLISH, LIQUID FILLER AND LIQUID LACQUER BASE) OR (INCLUDING PAINT THINNING OR REDUCING COMPOUND) o IMDG Page Number: 3268 UN Number: 1263 UN Hazard Class: 3.2 IMO Packaging Group: I/II * Subsidiary Risk Label: - EMS Number: 3-05 MED First Aid Guide NUM: 310 ======================================================= Detail IATA Information ======================================================= IATA PSN Code: SXI IATA UN ID Num: 1263 IATA Proper Shipping Name: PAINT IATA PSN Modifier: (INCLUDING PAINT,LACQUER,ENAMEL,STAIN,SHELLAC,VARNISH,POLISH,LIQUID FILLER AND LIQUID LACQUER BASE) IATA UN Class: 3 IATA Label: FLAMMABLE LIQUID UN Packing Group: II Packing Note Passenger: 305 Max Quant Pass: 5L Max Quant Cargo: 60L Packaging Note Cargo: 307 Exceptions: A7,A72 ======================================================= Detail AFI Information ======================================================= AFI PSN Code: SXI AFI Proper Shipping Name: PAINT OR PAINT RELATED MATERIAL AFI PSN Modifier: (INCLUDING PAINT,LACQUER,ENAMEL,STAIN,SHELLAC SOLUTIONS,VARNISH,POLISH,LIQUID FILLER AND LIQUID LACQUER BASE) OR (INCLUDING PAINT THINNING OR REDUCING COMPOUNDS) AFI Hazard Class: 3 AFI UN ID NUM: UN1263 AFI Packing Group: II Special Provisions: P5 Back Pack Reference: A7.3 ======================================================= HAZCOM Label ======================================================= Product ID: EUROPEAN SECRETS NAIL LACQUER Cage: 6N767 Company Name: AMERICAN INTERNATIONAL CHEMICAL INC Street: 17 STRATHMORE RD City: NATICK MA Zipcode: 01760 Health Emergency Phone: 213-728-2999 800-424-9300(CHEMTREC) Label Required IND: Y Date Of Label Review: 12/05/1997 Status Code: C MFG Label NO: UNKNOWN Label Date: 12/05/1997 Origination Code: F Eye Protection IND: YES Skin Protection IND: YES Signal Word: WARNING Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Moderate Reactivity Hazard: None Hazard And Precautions: EYES:MAY CAUSE IRRITATION.SKIN:MAY CAUSE IRRITATION.INHAL:MAY CAUSE RESPIRATORY IRRITATION AND CNS DEPRESSION.INGEST:MAY CAUSE GASTROINTESTINAL IRRITATION.CHRONIC:LONG TERM EXPOSURE TO THE SOLVENTS IN THIS PRODUCT HAVE BEEN ASSOCIATED WITH PERMANENT BRAIN AND NERVIOUS SYSTEM DAMAGE. FIRST AID: EYES:FLUSH WITH WATER UNTIL ALL TRACES OF THIS MATERIAL ARE GONE.SKIN:REMOVE CONTAMINATED CLOTHING.WASH WITH WATER.INHAL:REMOVE FROM EXPOSURE.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NE SCESSARY.INGEST:DO NOT INDUCE VOMITING.GET PROMPT QUALIFIED MEDICAL ATTENTION. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.