PROCTER & GAMBLE -- CASCADE (AUTOMATIC DISHWASHING DETERGENT) - DISHWASHING COMPOUND, MACHINE MATERIAL SAFETY DATA SHEET NSN: 7930006092555 Manufacturer's CAGE: 74188 Part No. Indicator: A Part Number/Trade Name: CASCADE (AUTOMATIC DISHWASHING DETERGENT) =========================================================================== General Information =========================================================================== Item Name: DISHWASHING COMPOUND, MACHINE Company's Name: PROCTER AND GAMBLE Company's Street: IVORYDALE TECHNICAL CENTER Company's City: CINCINNATI Company's State: OH Company's Country: US Company's Zip Code: 45217 Company's Emerg Ph #: 800-543-0485 Company's Info Ph #: 800-543-0485 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Status: SMJ Date MSDS Prepared: 01FEB90 Safety Data Review Date: 04FEB92 MSDS Serial Number: BMSNQ Hazard Characteristic Code: N/ =========================================================================== Ingredients/Identity Information =========================================================================== Proprietary: NO Ingredient: SODIUM MONOHYDROGEN PHOSPHATE HEPTAHYDRATE (2:1:1:7); (SODIUM PHOSPHATE) Ingredient Sequence Number: 01 NIOSH (RTECS) Number: WC4600000 CAS Number: 7682-85-6 OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: PEROXYDICARBONIC ACID, DISODIUM SALT;(SODIUM CARBONATE) Ingredient Sequence Number: 02 NIOSH (RTECS) Number: SD9920000 CAS Number: 3313-92-6 OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: NONIONIC SURFACTANTS Ingredient Sequence Number: 03 NIOSH (RTECS) Number: 1000978NS OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: HYPOCHLOROUS ACID, SODIUM SALT;(CHLORINE BLEACH) Ingredient Sequence Number: 04 NIOSH (RTECS) Number: NH3486300 CAS Number: 7681-52-9 OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: SILICIC ACID (H2SIO3), DISODIUM SALT;(SODIUM SILICATE) Ingredient Sequence Number: 05 NIOSH (RTECS) Number: VV9275000 CAS Number: 6834-92-0 OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: SODIUM SULFATE (2:1) Ingredient Sequence Number: 06 NIOSH (RTECS) Number: WE1650000 CAS Number: 7757-82-6 OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: SUDS CONTROL AGENT Ingredient Sequence Number: 07 NIOSH (RTECS) Number: 1005257SC OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: COLORANT Ingredient Sequence Number: 08 NIOSH (RTECS) Number: 1001827CO OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: PERFUME, TYPE UNSPECIFIED Ingredient Sequence Number: 09 NIOSH (RTECS) Number: 1000511PU OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE =========================================================================== Physical/Chemical Characteristics =========================================================================== Appearance And Odor: LIGHT BLUE GRANULAR AGGLOMERATE W/LOW LEVEL WHITE GRANULAR ADMIX. PERFUMED. Boiling Point: N/A Vapor Pressure (MM Hg/70 F): N/A Vapor Density (Air=1): N/A Specific Gravity: 1.0 G/CC Evaporation Rate And Ref: NOT APPLICABLE Solubility In Water: APPRECIABLE =========================================================================== Fire and Explosion Hazard Data =========================================================================== Flash Point: NOT APPLICABLE Lower Explosive Limit: N/A Upper Explosive Limit: N/A Extinguishing Media: CO*2, WATER, OR DRY CHEMICAL. Special Fire Fighting Proc: WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire And Expl Hazrds: NONE. =========================================================================== Reactivity Data =========================================================================== Stability: YES Cond To Avoid (Stability): NONE. Materials To Avoid: NONE. Hazardous Decomp Products: NONE. Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT RELEVANT. =========================================================================== Health Hazard Data =========================================================================== LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: INGEST:MAY CAUSE VOMITING AND TRANSIENT, MODERATE GI IRRITATION. EYE:MAY CAUSE MODERATE, TRANSIENT IRRITATION. INHAL:HEAVY OR PROLONGED EXPOSURE TO DUST MAY CAUSE TRANSIENT RESPIRATORY TRACT IRRITATION. SKIN:TRANSIENT IRRITATION WITH PROLONGED EXPOSURE TO CONCENTRATED MATERIAL. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NOT RELEVANT. Signs/Symptoms Of Overexp: INGEST:MAY RESULT IN NAUSEA, VOMITING, AND/ OR DIARRHEA. EYE:MAY CAUSE STINGING, TEARING, ITCHING, SWELLING AND/OR REDNESS. INHAL:MAY CAUSE COUGHING, SORE THROAT, WHEEZING, OR TRANSITORY SHORTNESS OF BREATH. SKIN:CONTACT WITH CONCENTRATED MATERIAL MAY BE DRYING OR TRANSIENTLY IRRITATING TO SKIN. Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER. Emergency/First Aid Proc: INGEST:DRINK A GLASSFUL OF WATER OR MILK. IF PROLONGED CONTACT OCCURS, RINSE THOROUGHLY WITH WATER. IF SYMPTOMS PERSIST OR REOCCUR, GET MD. =========================================================================== Precautions for Safe Handling and Use =========================================================================== Steps If Matl Released/Spill: COLLECT & PLACE IN SUITABLE CONTAINER & DISPOSE AS DRY SCRAP, OR FLUSH WITH WATER DOWN ACCEPTABLE SEWER (CONTAINS BIODEGRADABLE SURFACTANTS). PREVENT SPILLS FROM REACHING A WATERWAY. PREVENT HEAVY EXPOSURE TO DUST WITH NIOSH/MSHA APPROVED DUST MASK. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Method: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE W/ALL LOC, STATE & FED REGS. SMALL OR HOUSEHOLD QTYS MAY BE DISPOSED OF IN REFUSE OR IN SEWER. LARGER QUANTITIES OF CONTAMINATED OR WASTE MATL MAY BE DISPOSED OF IN MUNICIPAL LANDFILL WHERE ALLOWED BY LAW. Precautions-Handling/Storing: NO UNUSUAL PRECAUTIONS NECESSARY. AVOID CONTACT OF CARTONS WITH MOISTURE TO AVOID DISPENSING PROBLEMS. Other Precautions: CAUTION:HARMFUL IF SWALLOWED. EYE IRRITANT. KEEP OUT OF REACH OF CHILDREN. =========================================================================== Control Measures =========================================================================== Respiratory Protection: NONE REQUIRED WITH NORMAL USE. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: NORMAL/GENERAL DILUTION VENTILATION IS ACCEPTABLE. Protective Gloves: RUBBER/NEOPRENE GLOVES FOR PRLNGD USE. Eye Protection: CHEMICAL WORKERS GOGGLES (FP N). Other Protective Equipment: NONE REQUIRED WITH NORMAL USE. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Suppl. Safety & Health Data: NONE SPECIFIED BY MANUFACTURER. =========================================================================== Transportation Data =========================================================================== Trans Data Review Date: 92128 DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION AFI PSN Code: ZZZ AFI Prop. Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION Additional Trans Data: NOT REGULATED FOR TRANSPORTATION =========================================================================== Disposal Data =========================================================================== =========================================================================== Label Data =========================================================================== Label Required: YES Technical Review Date: 12FEB92 Label Date: 12FEB92 Label Status: G Common Name: CASCADE (AUTOMATIC DISHWASHING DETERGENT) Chronic Hazard: NO Signal Word: CAUTION! Acute Health Hazard-Slight: X Contact Hazard-Slight: X Fire Hazard-None: X Reactivity Hazard-None: X Special Hazard Precautions: ACUTE:INGESTION MAY CAUSE MODERATE, TRANSIENT GASTROINTESTINAL IRRITATION, VOMITING, NAUSEA AND/OR DIARRHEA. CONTACT WITH EYES MAY CAUSE MODERATE, TRANSIENT IRRITATION, STINGING, TEARING, ITCHING, SWELLING AND/OR REDNESS. INHALATION OF DUST MAY CAUSE TRANSIENT RESPIRATORY TRACT IRRITATION, COUGHING, SORE THROAT, WHEEZING OR TRANSITORY SHORTNESS OF BREATH. SKIN CONTACT WITH CONCENTRATED MATERIAL MAY CAUSE TRANSIENT IRRITATION OR DRYING. CHRONIC:NONE LISTED BY MANUFACTURER. Protect Eye: Y Protect Skin: Y Protect Respiratory: Y Label Name: PROCTER AND GAMBLE Label Street: IVORYDALE TECHNICAL CENTER Label City: CINCINNATI Label State: OH Label Zip Code: 45217 Label Country: US Label Emergency Number: 800-543-0485